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• W2017452894 abstract "By means of synchrotron x-ray and electron diffraction, we studied the structural changes at the charge order transition $T_{CO}$=176 K in the mixed-valence quadruple perovskite (NaMn$_3$)Mn$_4$O$_{12}$. Below $T_{CO}$ we find satellite peaks indicating a commensurate structural modulation with the same propagation vector q =(1/2,0,-1/2) of the CE magnetic order that appears at low temperature, similarly to the case of simple perovskites like La$_{0.5}$Ca$_{0.5}$MnO$_3$. In the present case, the modulated structure together with the observation of a large entropy change at $T_{CO}$ gives evidence of a rare case of full Mn$^{3+}$/Mn$^{4+}$ charge and orbital order consistent with the Goodenough-Kanamori model." @default.
• W2017452894 created "2016-06-24" @default.
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• W2017452894 date "2014-11-10" @default.
• W2017452894 modified "2023-09-25" @default.
• W2017452894 title "Commensurate structural modulation in the charge- and orbitally ordered phase of the quadruple perovskite<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML><mml:mo>(</mml:mo><mml:msub><mml:mi mathvariant=normal>NaMn</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:msub><mml:mi mathvariant=normal>Mn</mml:mi><mml:mn>4</mml:mn></mml:msub><mml:msub><mml:mi mathvariant=normal>O</mml:mi><mml:mn>12</mml:mn></mml:msub></mml:math>" @default.
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• W2017452894 doi "https://doi.org/10.1103/physrevb.90.180101" @default.
• W2017452894 hasPublicationYear "2014" @default.
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