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- W2017453503 abstract "Abstract The mechanical relaxation behaviors of oriented samples of a linear low-density polyethylene (LLDPE) and a high-density polyethylene (HDPE) were studied using tensile dynamic mechanical measurements. The anisotropy and activation energies of the relaxations were determined for several different samples to investigate why the α-relaxation in HDPE has characteristics similar in some respects to both the α- and β-relaxations in LLDPE. It is concluded that the anisotropy of the α-relaxation in LLDPE is determined by c-shear, whereas in HDPE it relates to interlamellar shear. The activation energy measurements, however, show that the thermally activated process for the α-relaxation in both the LLDPE and HDPE is c-shear. It is proposed that, in HDPE, c-shear has to occur before there is enough mobility at the fold surface for interlamellar shear. It is concluded that the β-relaxation is not observed in HDPE because the interlamellar regions are too constrained to allow interlamellar shear without c-shear." @default.
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- W2017453503 date "1999-01-01" @default.
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- W2017453503 title "A comparison of the dynamic mechanical relaxation behavior of linear low- and high-density polyethylenes" @default.
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- W2017453503 doi "https://doi.org/10.1080/00222349908248110" @default.
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