Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017457281> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2017457281 endingPage "81" @default.
- W2017457281 startingPage "71" @default.
- W2017457281 abstract "Abstract This article reports on the cleavage of lignin β-aryl ether bonds in sugarcane bagasse by the ionic liquid (IL) trihexyl tetradecyl phosphonium chloride [P66614] Cl, in the presence of catalytic amounts of mineral acid (ca. 0.4%). The delignification process of bagasse was studied over a range of temperatures (120°C to 150°C) by monitoring the production of β-ketones (indicative of cleavage of β-aryl ethers) using FTIR spectroscopy and by compositional analysis of the undissolved fractions. Maximum delignification was obtained at 150°C, with 52% of lignin removed from the original lignin content of bagasse. No delignification was observed in the absence of acid, which suggests that the reaction is acid catalyzed with the IL solubilizing the lignin fragments. The rate of delignification was significantly higher at 150°C, suggesting that crossing the glass transition temperature of lignin effects greater freedom of rotation about the propanoid carbon-carbon bonds and leads to increased cleavage of β-aryl ethers. An attempt has been made to propose a probable mechanism of delignification of bagasse with the phosphonuim IL." @default.
- W2017457281 created "2016-06-24" @default.
- W2017457281 creator A5027179474 @default.
- W2017457281 creator A5027454523 @default.
- W2017457281 creator A5030135351 @default.
- W2017457281 creator A5032299857 @default.
- W2017457281 date "2012-01-01" @default.
- W2017457281 modified "2023-10-14" @default.
- W2017457281 title "The Chemistry of Acid Catalyzed Delignification of Sugarcane Bagasse in the Ionic Liquid Trihexyl Tetradecyl Phosphonium Chloride" @default.
- W2017457281 cites W1975298007 @default.
- W2017457281 cites W1976247623 @default.
- W2017457281 cites W1980836177 @default.
- W2017457281 cites W1984769267 @default.
- W2017457281 cites W1987931160 @default.
- W2017457281 cites W2021916337 @default.
- W2017457281 cites W2027542544 @default.
- W2017457281 cites W2028557760 @default.
- W2017457281 cites W2043117267 @default.
- W2017457281 cites W2052563747 @default.
- W2017457281 cites W2054597255 @default.
- W2017457281 cites W2066625392 @default.
- W2017457281 cites W2080125304 @default.
- W2017457281 cites W2081658730 @default.
- W2017457281 cites W2100231888 @default.
- W2017457281 cites W2103207805 @default.
- W2017457281 cites W2110919001 @default.
- W2017457281 cites W2131382161 @default.
- W2017457281 cites W2135717691 @default.
- W2017457281 cites W2149816055 @default.
- W2017457281 cites W2163075518 @default.
- W2017457281 cites W2165861896 @default.
- W2017457281 cites W2166109955 @default.
- W2017457281 doi "https://doi.org/10.1080/02773813.2011.573120" @default.
- W2017457281 hasPublicationYear "2012" @default.
- W2017457281 type Work @default.
- W2017457281 sameAs 2017457281 @default.
- W2017457281 citedByCount "12" @default.
- W2017457281 countsByYear W20174572812012 @default.
- W2017457281 countsByYear W20174572812013 @default.
- W2017457281 countsByYear W20174572812014 @default.
- W2017457281 countsByYear W20174572812015 @default.
- W2017457281 countsByYear W20174572812016 @default.
- W2017457281 countsByYear W20174572812020 @default.
- W2017457281 countsByYear W20174572812022 @default.
- W2017457281 crossrefType "journal-article" @default.
- W2017457281 hasAuthorship W2017457281A5027179474 @default.
- W2017457281 hasAuthorship W2017457281A5027454523 @default.
- W2017457281 hasAuthorship W2017457281A5030135351 @default.
- W2017457281 hasAuthorship W2017457281A5032299857 @default.
- W2017457281 hasConcept C127413603 @default.
- W2017457281 hasConcept C134643618 @default.
- W2017457281 hasConcept C13965031 @default.
- W2017457281 hasConcept C154881586 @default.
- W2017457281 hasConcept C161790260 @default.
- W2017457281 hasConcept C178790620 @default.
- W2017457281 hasConcept C185592680 @default.
- W2017457281 hasConcept C2777329087 @default.
- W2017457281 hasConcept C2778695967 @default.
- W2017457281 hasConcept C2780263894 @default.
- W2017457281 hasConcept C2780407432 @default.
- W2017457281 hasConcept C2780707935 @default.
- W2017457281 hasConcept C2781052789 @default.
- W2017457281 hasConcept C2781076698 @default.
- W2017457281 hasConcept C528095902 @default.
- W2017457281 hasConceptScore W2017457281C127413603 @default.
- W2017457281 hasConceptScore W2017457281C134643618 @default.
- W2017457281 hasConceptScore W2017457281C13965031 @default.
- W2017457281 hasConceptScore W2017457281C154881586 @default.
- W2017457281 hasConceptScore W2017457281C161790260 @default.
- W2017457281 hasConceptScore W2017457281C178790620 @default.
- W2017457281 hasConceptScore W2017457281C185592680 @default.
- W2017457281 hasConceptScore W2017457281C2777329087 @default.
- W2017457281 hasConceptScore W2017457281C2778695967 @default.
- W2017457281 hasConceptScore W2017457281C2780263894 @default.
- W2017457281 hasConceptScore W2017457281C2780407432 @default.
- W2017457281 hasConceptScore W2017457281C2780707935 @default.
- W2017457281 hasConceptScore W2017457281C2781052789 @default.
- W2017457281 hasConceptScore W2017457281C2781076698 @default.
- W2017457281 hasConceptScore W2017457281C528095902 @default.
- W2017457281 hasIssue "1" @default.
- W2017457281 hasLocation W20174572811 @default.
- W2017457281 hasOpenAccess W2017457281 @default.
- W2017457281 hasPrimaryLocation W20174572811 @default.
- W2017457281 hasRelatedWork W2017457281 @default.
- W2017457281 hasRelatedWork W2026139859 @default.
- W2017457281 hasRelatedWork W2044380408 @default.
- W2017457281 hasRelatedWork W2051324133 @default.
- W2017457281 hasRelatedWork W2071746505 @default.
- W2017457281 hasRelatedWork W2098558767 @default.
- W2017457281 hasRelatedWork W2132747920 @default.
- W2017457281 hasRelatedWork W2168140010 @default.
- W2017457281 hasRelatedWork W2794174117 @default.
- W2017457281 hasRelatedWork W4301524474 @default.
- W2017457281 hasVolume "32" @default.
- W2017457281 isParatext "false" @default.
- W2017457281 isRetracted "false" @default.
- W2017457281 magId "2017457281" @default.
- W2017457281 workType "article" @default.