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- W2017469460 abstract "In an attempt to find the structural features promoting the thermal isomerization of the N-acylated steroid[16,17-d]pyrazoles into [17,16-c]pyrazole derivatives, the X-ray structure analysis of the title compound, C 23 H 30 N 2 O 3 , (I), has been carried out. The steroid moiety of (I) has the usual conformation. The dihedral angle between the planar pyrazole ring and the N-acetyl group is very small [5.6(2) o ], but the amide C-N bond seems to be substantially elongated [1.404(3) A]. The d-pyrazole ring junction via a double bond leads to deformations of some bond and torsion angles, which would be decreased in the case of a ring junction via a single bond in the [17,16-c]pyrazole isomer" @default.
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- W2017469460 date "1994-12-15" @default.
- W2017469460 modified "2023-09-25" @default.
- W2017469460 title "N1-Acetyl-3'-methylandrosta-4,16-dieno[16,17-d]pyrazole-3-one" @default.
- W2017469460 doi "https://doi.org/10.1107/s0108270194004737" @default.
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