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• W2017474493 abstract "Abstract The magnetic susceptibility of Pb1-xCexA (A=S, Se and Te) crystals with Ce3+ concentrations 0.006≤x≤0.036 was investigated in the temperature range from 2 K to 300 K. The magnetic susceptibility data was found to be consistent with a 2F5/2 lowest manifold for Ce3+ ions with a crystal-field splitting Δ=E(Γ8)−E(Γ7) of about 340 K, 440 K and 540 K for Pb1-xCexTe, Pb1-xCexSe, and Pb1-xCexS, respectively. For all the three compounds the doublet Γ7 lies below the Γ8 quadruplet which confirms the substitution of Pb2+ by Ce3+ ions in the host crystals. The observed values for the crystal-field splitting are in good agreement with the calculated ones based on the point-charge model. Moreover, the effective Lande factors were determined by X-band (∼9.5 GHz), electron paramagnetic measurements (EPR) to be g=1.333, 1.364, and 1.402 for Ce ions in PbA, A = S, Se and Te, respectively. The small difference with the predicted Lande factor g of 10/7 for the Γ7 (J=5/2) ground state was attributed to crystal-field admixture." @default.
• W2017474493 created "2016-06-24" @default.
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• W2017474493 date "2012-09-01" @default.
• W2017474493 modified "2023-09-24" @default.
• W2017474493 title "Magnetic susceptibility study of Ce3+ in PbCeA (A=Te, Se, S)" @default.
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• W2017474493 doi "https://doi.org/10.1016/j.jmmm.2012.04.004" @default.
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