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- W2017479972 abstract "We use B-spline basis sets to consider the influence of complete series (i.e. discrete states + continuum) on a perturber. In particular we calculate the interaction between the nsnp6 2 S term and the ns2np4(1D)md/ epsilon d2S Rydberg series in Ar II (n = 3) and Kr II(n = 4) and between the 3s3p5 3 P term and the 3p3(2D)nd/ epsilon d3P, 3p3(2P)nd/ epsilon d3P and 3p3(2P)ns/ epsilon s 3p Rydberg series in S I. Energies and eigenvectors are calculated for the lower part of the bound spectrum. In Ar II and Kr II, we use these to calculate the strength of the satellite spectrum following 3s ionization in Ar and 4s ionization in Kr. In the case of S I we calculate oscillator strengths for transitions to the ground state and discuss the identification of the observed photoabsorption spectra. The results are compared with other theoretical calculations and with experimental results. We discuss the determination of the B-spline basis as a solution to the frozen core HF equations. We show that use of a rather limited B-spline basis is a very efficient way to approximate a complete (bound + continuum) Rydberg series." @default.
- W2017479972 created "2016-06-24" @default.
- W2017479972 creator A5003802515 @default.
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- W2017479972 date "1993-10-14" @default.
- W2017479972 modified "2023-10-17" @default.
- W2017479972 title "Calculations of strong interactions between a perturber and one or several series using B-spline basis sets" @default.
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- W2017479972 doi "https://doi.org/10.1088/0953-4075/26/19/012" @default.
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