Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017485519> ?p ?o ?g. }
Showing items 1 to 99 of
99
with 100 items per page.
- W2017485519 endingPage "277" @default.
- W2017485519 startingPage "271" @default.
- W2017485519 abstract "Nafion-H was used as a solid acid catalyst for the Koch-type carbonylation of alcohols. The carbonylation of a variety of primary, secondary and tertiary alcohols in various solvents such as hexane, cyclohexane, dichloromethane and chlorobenzene produces the corresponding tertiary carboxylic acids in high yields. For example, the conversions of 2-methyl-2-propanol, 1-pentanol and 1-adamantanol to carboxylic acids are 62.5, 64.6 and 76.9%, respectively, at 433 K and 9 MPa CO. The optimum temperature for this reaction is between 433 and 443 K. A high CO pressure is advantageous for the carbonylation. Only small amounts of ethers were observed for the primary alcohols under CO pressure and without water removal, in contrast with the previous report that primary alcohols are converted to ethers over Nafion-H in quantitative yields when CO is absent and water is removed by azeotropic distillation." @default.
- W2017485519 created "2016-06-24" @default.
- W2017485519 creator A5032557269 @default.
- W2017485519 creator A5063108303 @default.
- W2017485519 creator A5063368837 @default.
- W2017485519 creator A5064109029 @default.
- W2017485519 date "2002-02-01" @default.
- W2017485519 modified "2023-10-14" @default.
- W2017485519 title "Carbonylation of alcohols over Nafion-H, a solid perfluoroalkanesulfonic acid resin catalyst" @default.
- W2017485519 cites W144236234 @default.
- W2017485519 cites W1997297699 @default.
- W2017485519 cites W2015176992 @default.
- W2017485519 cites W2021899938 @default.
- W2017485519 cites W2025348041 @default.
- W2017485519 cites W2029418916 @default.
- W2017485519 cites W2035401109 @default.
- W2017485519 cites W2061221675 @default.
- W2017485519 cites W2062845999 @default.
- W2017485519 cites W2067429624 @default.
- W2017485519 cites W2079622797 @default.
- W2017485519 cites W2090385934 @default.
- W2017485519 cites W2136212049 @default.
- W2017485519 cites W2325317931 @default.
- W2017485519 cites W2949847182 @default.
- W2017485519 cites W2950711738 @default.
- W2017485519 cites W2951470368 @default.
- W2017485519 cites W2953249063 @default.
- W2017485519 cites W3012803373 @default.
- W2017485519 cites W4250811699 @default.
- W2017485519 cites W578652574 @default.
- W2017485519 doi "https://doi.org/10.1016/s1381-1169(01)00396-x" @default.
- W2017485519 hasPublicationYear "2002" @default.
- W2017485519 type Work @default.
- W2017485519 sameAs 2017485519 @default.
- W2017485519 citedByCount "17" @default.
- W2017485519 countsByYear W20174855192012 @default.
- W2017485519 countsByYear W20174855192014 @default.
- W2017485519 countsByYear W20174855192019 @default.
- W2017485519 countsByYear W20174855192020 @default.
- W2017485519 countsByYear W20174855192021 @default.
- W2017485519 countsByYear W20174855192022 @default.
- W2017485519 crossrefType "journal-article" @default.
- W2017485519 hasAuthorship W2017485519A5032557269 @default.
- W2017485519 hasAuthorship W2017485519A5063108303 @default.
- W2017485519 hasAuthorship W2017485519A5063368837 @default.
- W2017485519 hasAuthorship W2017485519A5064109029 @default.
- W2017485519 hasConcept C147789679 @default.
- W2017485519 hasConcept C161790260 @default.
- W2017485519 hasConcept C168382676 @default.
- W2017485519 hasConcept C17525397 @default.
- W2017485519 hasConcept C178790620 @default.
- W2017485519 hasConcept C185592680 @default.
- W2017485519 hasConcept C204030448 @default.
- W2017485519 hasConcept C2776041390 @default.
- W2017485519 hasConcept C2778237882 @default.
- W2017485519 hasConcept C2778665636 @default.
- W2017485519 hasConcept C2779074116 @default.
- W2017485519 hasConcept C2780400988 @default.
- W2017485519 hasConcept C2780471494 @default.
- W2017485519 hasConcept C2781066024 @default.
- W2017485519 hasConcept C512735826 @default.
- W2017485519 hasConcept C52859227 @default.
- W2017485519 hasConceptScore W2017485519C147789679 @default.
- W2017485519 hasConceptScore W2017485519C161790260 @default.
- W2017485519 hasConceptScore W2017485519C168382676 @default.
- W2017485519 hasConceptScore W2017485519C17525397 @default.
- W2017485519 hasConceptScore W2017485519C178790620 @default.
- W2017485519 hasConceptScore W2017485519C185592680 @default.
- W2017485519 hasConceptScore W2017485519C204030448 @default.
- W2017485519 hasConceptScore W2017485519C2776041390 @default.
- W2017485519 hasConceptScore W2017485519C2778237882 @default.
- W2017485519 hasConceptScore W2017485519C2778665636 @default.
- W2017485519 hasConceptScore W2017485519C2779074116 @default.
- W2017485519 hasConceptScore W2017485519C2780400988 @default.
- W2017485519 hasConceptScore W2017485519C2780471494 @default.
- W2017485519 hasConceptScore W2017485519C2781066024 @default.
- W2017485519 hasConceptScore W2017485519C512735826 @default.
- W2017485519 hasConceptScore W2017485519C52859227 @default.
- W2017485519 hasIssue "1-2" @default.
- W2017485519 hasLocation W20174855191 @default.
- W2017485519 hasOpenAccess W2017485519 @default.
- W2017485519 hasPrimaryLocation W20174855191 @default.
- W2017485519 hasRelatedWork W1946108076 @default.
- W2017485519 hasRelatedWork W2017485519 @default.
- W2017485519 hasRelatedWork W2038063204 @default.
- W2017485519 hasRelatedWork W2053186615 @default.
- W2017485519 hasRelatedWork W2088669026 @default.
- W2017485519 hasRelatedWork W2147427301 @default.
- W2017485519 hasRelatedWork W2386173067 @default.
- W2017485519 hasRelatedWork W2936528509 @default.
- W2017485519 hasRelatedWork W2949605739 @default.
- W2017485519 hasRelatedWork W4252504590 @default.
- W2017485519 hasVolume "179" @default.
- W2017485519 isParatext "false" @default.
- W2017485519 isRetracted "false" @default.
- W2017485519 magId "2017485519" @default.
- W2017485519 workType "article" @default.