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- W2017490116 abstract "The stibocane O(CH2CH2S)2SbS2P(OC2H5)2 (1) was prepared by reacting O(CH2CH2S)2SbCl and KS2P(OC2H5)2, in anhydrous benzene, and characterized by spectroscopic (IR, MS, 1H, 13C and 31P1H NMR) methods. The crystal and molecular structure of O(CH2CH2S)2SbSCH2CH2OCH2CH2SSb(SCH2CH2)2O (2), obtained as a side product during the attempts to grow crystals of the dithiophosphato derivative, was determined by X-ray diffractometry. The compound is triclinic, space group P1, a = 7.994(1), b = 10.495(1), c = 14.562(2) Å, α = 77.90(1), β = 85.50(1), γ = 69.02(1)°, V = 1115.3(2) Å3, Z = 2. The molecule of 2 contains two SbS2C4O rings with different conformations, i.e. chair-chair for Sb(1) and boat-chair for Sb(2). In both heterocyclic rings strong transannular Sb(1)…O(1) (2.734(3) Å) and Sb(2)…O(3) (2.637(4) Å) interactions are present. The O(2) atom of the bridging ligand also exhibits intramolecular Sb(1)…O(2) (2.895(3) Å) and Sb(2)…O(2) (3.156(3) Å) interactions. In the crystal form 2 is associated in pairs through weak, intermolecular Sb(2)…S secondary interactions (3.733(1) Å), thus resulting in different coordination polyhedra for the antimony atoms in the same molecule." @default.
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- W2017490116 title "On the 5-thia-(substituted)-1-oxa-4,6-dithia-5-stibocanes. Synthesis and characterization of O(CH2CH2S)2SbS2P(OC2H5)2 and crystal and molecular structure of (CH2CH2S)2SbSCH2CH2OCH2CH2SSb(SCH2CH2)2O, a compound with two different eight-membered ring conformations" @default.
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- W2017490116 doi "https://doi.org/10.1016/0020-1693(95)04602-6" @default.
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