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- W2017492721 abstract "Proving the preservation of functionality at the molecular scale is still a major challenge, both for the choice of suitable derivatives and protocols and for the employed experimental tools and methods. By using a combined scanning probe (AFM and STM) and spectroscopic methodology (XPS, XAS and XMCD), it is shown that Gd4M8 derivatives (with M = Zn2+, Ni2+) are robust molecular units which preserve their electronic, magnetic, and thermodynamic properties when deposited on a metallic surface. Namely, entropy variation ΔS = [S(6 T) – S(0 T)] exceeding 8 R (20 J kg−1 K−1) at 4 K in isolated Gd4Ni8 molecules dispersed on Au(111) surface is measured and a viable route to exploit large magnetocaloric effect at single molecule level is shown." @default.
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- W2017492721 date "2014-05-05" @default.
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- W2017492721 title "Surface Investigation on Gd<sub>4</sub>M<sub>8</sub>(M = Zn, Ni) Single Molecule Coolers" @default.
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- W2017492721 doi "https://doi.org/10.1002/adfm.201400460" @default.
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