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- W2017492800 abstract "Three O+vinylhalide reactions were studied to identify the reactive channels, determine the overall rate constants and to measure the specific rate constants for each important open channel. Products were identified by studying these reactions in high-intensity crossed molecular beams. Each O+C2H3X (X=F, Cl, or Br) reaction was found to proceed by three major routes producing: 1, CH3+XCO (X+CO); 2, CH2X+HCO; and 3, H2C2O+HX. Minor routes were also observed. Specific rate constants for routes 1 and 3 as well as overall rate constants were obtained for all three O+vinylhalide reactions and were used to calculate branching ratios for the major routes of these three reactions at 302°K. Possible mechanisms for these reactions are discussed." @default.
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- W2017492800 date "1975-01-01" @default.
- W2017492800 modified "2023-09-23" @default.
- W2017492800 title "Direct identification of products and measurement of branching ratios for the reactions of oxygen atoms with vinylfluoride, vinylchloride, and vinylbromide" @default.
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- W2017492800 doi "https://doi.org/10.1016/s0082-0784(75)80347-x" @default.
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