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• W2017498790 abstract "A series of molten salts EMIm(HF)nF's with different n values has been synthesized by the reaction of EMImHF(2) and anhydrous hydrogen fluoride. The salts contain EMIm cation and some oligomeric fluorohydrogenate anions, (HF)nF-, of which the fraction changes with the change of n. A phase diagram of EMIm(HF)nF's (n = 1.0-2.6) has been constructed which suggests the presence of the stoichiometric compounds, EMIm(HF)1.5F and EMIm(HF)2F, in this range. Compared to the EMIm(HF)2.3F previously reported, EMIm(HF)nF's (n = 1.8-2.0) possess wider liquid temperature ranges because of their similar melting points and superior thermal stabilities at elevated temperatures. The electrochemical windows of EMIm(HF)nF's (n = 1.0-2.6) falls in the range of 2.9-3.4 V. The conductivity of EMIm(HF)nF's (n = 1.0-2.6) increases with the increase of n." @default.
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• W2017498790 date "2005-03-01" @default.
• W2017498790 modified "2023-10-14" @default.
• W2017498790 title "The Effect of the Anion Fraction on the Physicochemical Properties of EMIm(HF)<i>_n</i>F (<i>n</i> = 1.0−2.6)" @default.
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• W2017498790 doi "https://doi.org/10.1021/jp047006l" @default.
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