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- W2017503103 abstract "Upon mixing and dehydration, 2,6-diformylpyridine and 2,2‘-oxybis(ethylamine) form a dynamic combinatorial library of at least nine members. Through hydrogen bonding and other intermolecular interactions, templating dumbbell molecules select one macrocyclic member of the library, at the expense of all the others, to create [2]rotaxanes. These rotaxanes, however, retain the dynamic character of the library, since a diformylpyridine analogue can exchange with the macrocyclic component in solution. In addition, crystallization of the mixture surprisingly furnishes only the [24]crown-8-like macrocycle on its ownevidence of a kinetic selection process occurring between phase transitions." @default.
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- W2017503103 date "2007-08-08" @default.
- W2017503103 modified "2023-10-15" @default.
- W2017503103 title "Equilibrating Dynamic [2]Rotaxanes" @default.
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- W2017503103 doi "https://doi.org/10.1021/jo0708590" @default.
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