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• W2017506189 abstract "Racemic naproxen amide (RS)-1 was hydrolyzed to enantiomerically pure naproxen (S)-2 in water-saturated organic solvents with log P values between 2.0 and 0.17 using immobilized resting cells of the bacterial strain Rhodococcus erythropolis MP50. Alkyl acetates are the most suitable solvents concerning solubility of (RS)-1 and enzyme activity. In butyl acetate with 3 vol% DMSO as cosolvent and an increased water content of the immobilized cells the rate of hydrolysis was an optimum. Under these reaction conditions a preparative scale application gave after 45 h, at a conversion rate of 48%, (S)-2 with >99% ee and an isolated yield of 84%." @default.
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• W2017506189 date "1997-08-01" @default.
• W2017506189 modified "2023-10-14" @default.
• W2017506189 title "Preparation of (S)-naproxen by enantioselective hydrolysis of racemic naproxen amide with resting cells of Rhodococcus erythropolis MP50 in organic solvents" @default.
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• W2017506189 doi "https://doi.org/10.1016/s0957-4166(97)00335-2" @default.
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