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- W2017507347 abstract "The host–guest interaction between symmetrical α,α′,δ,δ′-tetramethyl-cucurbit[6]uril (TMeQ[6]) and methylviologen (N,N′-dimethyl-4,4′-bipyridinium, MV) dication was investigated both in aqueous solution and in the solid state using NMR spectroscopic methods and single-crystal X-ray diffraction analysis. In the aqueous solution, TMeQ[6] forms a 1 : 1 inclusion complex with methylviologen MV2+, and the chemical exchange of the MV2+ guest in and out of the cavity of the TMeQ[6] host was fast on the NMR time scale. In the solid state, however, the MV2+ guest was partially encapsulated into the TMeQ[6] host. We found that the chemical environment of the TMeQ[6] host underwent a severe change during the encapsulation process. Interestingly, electrochemical studies revealed that, unlike other cucurbiturils, TMeQ[6] has the same level of binding affinity to the charged forms (MV2+ and MV+˙) and the fully reduced form (MV0). These studies contribute to the fundamental understanding of the interdependence of electron-transfer processes and molecular recognition." @default.
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- W2017507347 date "2012-01-01" @default.
- W2017507347 modified "2023-09-28" @default.
- W2017507347 title "Inclusion of methylviologen in symmetrical α,α′,δ,δ′-tetramethyl-cucurbit[6]uril" @default.
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- W2017507347 doi "https://doi.org/10.1039/c2ra20918g" @default.
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