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• W2017520100 abstract "By the reaction of a number of oligosilyl potassium compounds with (trimethylsilyl)chloromethane, derivatives containing the (trimethylsilyl)methyl substituent were prepared. Using X-ray single-crystal structure analysis and UV spectroscopy the conformational properties of some of the compounds were studied. It was found that the (trimethylsilyl)methylated examples exhibit UV absorption properties which correspond to lower energy transitions in comparison to those of analogous trimethylsilylated molecules. The influence of this effect decreases, however, with increasing chain lengths." @default.
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• W2017520100 date "2011-07-11" @default.
• W2017520100 modified "2023-10-14" @default.
• W2017520100 title "Conformational Control of Polysilanes: Use of CH₂ Spacers in the Silicon Backbone" @default.
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• W2017520100 doi "https://doi.org/10.1021/om1011159" @default.
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