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- W2017520199 abstract "Abstract 1,2-O-Alkylidene-α- d -glucofuranose 3,5,6-bicyclophosphites form optically active complexes with simple Cu(I), Cr(0), Mo(0) and Pt(II) derivatives. All these metals are coordinated to the phosphorus atom. It was shown that copper complexes in a solution are in rapid exchange with free ligands. Depending on the reaction conditions, chromium and molybdenum can add one or two ligand molecules. Cis–trans isomerization is typical for the phosphite complexes of platinum in the solution. The structural parameters of some synthesised complexes were compared with those of their nearest analogues on the basis of X-ray diffraction analysis. Relatively slight deformation of ligands coordinated was inferred. Most of the metal complexes obtained are quite stable and can be used in experimental practice." @default.
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- W2017520199 date "1999-09-01" @default.
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- W2017520199 title "Metal complexes based on monosaccharide bicyclophosphites as new available chiral coordination systems" @default.
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- W2017520199 doi "https://doi.org/10.1016/s0022-328x(99)00245-4" @default.
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