Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017524199> ?p ?o ?g. }
- W2017524199 endingPage "5425" @default.
- W2017524199 startingPage "5393" @default.
- W2017524199 abstract "Photo-iniferter (PI)–RAFT polymerization, the direct activation of chain transfer agents via light, is a fascinating polymerization technique, as it overcomes some restriction of conventional RAFT polymerization. As such, we elucidated the role of reversible deactivation in this context using a monomer–CTA pair with low chain transfer capabilities. Tests with varying targeted degrees of polymerization (DP) or monomer concentrations revealed no significant improvement of polymerization control using the PI-process. Control can however be achieved via slow monomer addition, increasing the number of activation/deactivation events per monomer addition. More importantly, the livingness of the polymerization was found to be extraordinarily high, enabling the straightforward and rapid synthesis of multiblock copolymers with up to 20 blocks and a high number of repeating units per block (DP = 25–100) maintaining an overall excellent definition (Mn = 90 300 g mol−1, Đ = 1.29). This study highlights the enormous potential of PI–RAFT polymerization for the synthesis of polymeric materials." @default.
- W2017524199 created "2016-06-24" @default.
- W2017524199 creator A5028398234 @default.
- W2017524199 date "1985-01-01" @default.
- W2017524199 modified "2023-10-11" @default.
- W2017524199 title "The photochemistry of thiocarbonyl compounds" @default.
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