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- W2017526090 abstract "The behavior of methoxy species on dimethyl ether (DME) adsorbed CeO2 was investigated using temperature-programmed desorption (TPD) and infrared (IR) spectroscopy. TPD experiments showed that the thermal desorption peaks at 470−500 and 570 K are all DME from DME/CeO2 adsorbed at 300 K. These DME desorptions are attributed to the recombination of the surface methoxy species on CeO2. IR spectra of DME-adsorbed CeO2 showed two bands at 1158 and 1070 cm-1 at 300 K. These bands were assigned to the C−O stretching (ν(CO)) bands of surface methoxy species bound to one Ce ion (terminal-OCH3) and two Ce ions (bridged-OCH3), respectively. These bands decreased with increasing the temperature of CeO2. The increase of the temperature to 490 K led to the appearance of a new band at 1025 cm-1 which was identified as ν(CO) of μ-OCH3 bound to more than three Ce ions. The TPD and IR results suggest that only the μ-OCH3 is decomposed into carbonate via a formate intermediate. The reactions of surface methoxy species on CeO2 are discussed." @default.
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- W2017526090 title "Thermal Conversion of Methoxy Species on Dimethyl Ether Adsorbed CeO<sub>2</sub>" @default.
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- W2017526090 doi "https://doi.org/10.1021/jp960891q" @default.
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