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• W2017555853 abstract "Crystals of Ph3Bi(OCOCF3)2 have been shown by X-ray diffractometry to be made up of isolated molecules in which the coordination at bismuth is intermediate between trigonal bipyramidal, with apipcal monodentate CF3COO groups and pentagonal bipyramidal with equatorial bidentate CF3COO groups. In the case of Ph3Sb(OCOCF3)2 there is essentially trigonal bipyramidal coordination at antimony, with apical CF3COO groups, and with a quite different conformation from that found for the bismuth compound." @default.
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• W2017555853 date "1991-01-01" @default.
• W2017555853 modified "2023-10-17" @default.
• W2017555853 title "High metal coordination numbers in group 15 organometallics: crystal structures of triphenylbismuthbis(trifluoroacetate) and triphenylantimonybis(trifluoroacetate)" @default.
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• W2017555853 doi "https://doi.org/10.1016/0022-328x(91)80241-b" @default.
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