Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017556648> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W2017556648 endingPage "122" @default.
- W2017556648 startingPage "114" @default.
- W2017556648 abstract "In order to determine the complete rs structure of methyl cyanate, the microwave spectra of 13CH3OCN, CH318OCN, CH3O13CN, sym-CH2DOCN, and asym-CH2DOCN have been observed in the frequency range from 7.5 to 50.0 GHz. From these data together with the already reported molecular constants of normal and 15N isotopic species, the following structural parameters [bond lengths in Å(1 Å = 0.1 nm) and angles in degrees] are obtained: r(C1H1) = 1.074(12), r(C1H2) = 1.075(25), r(C1O) = 1.455(1), r(OC2) = 1.302(3), r(C2N) = 1.146(3), 〈H1C1H2 = 110.4(22). 〈H2C1H2 = 110.7(35), 〈H1C1O = 106.5(11), 〈H2C1O = 109.4(14), 〈C1OC2 = 113.8(3), and 〈OC2N = 178.4(6). The rs structure of methyl cyanate indicates that the bond length of r(OC2) is much shorter than that of r(OC1) and that the OCN chain is slightly bent. The obtained structural parameters were very similar to those of methoxyethyne (CH3OCCH), which is an isoelectric molecule of methyl cyanate." @default.
- W2017556648 created "2016-06-24" @default.
- W2017556648 creator A5013893275 @default.
- W2017556648 creator A5014838749 @default.
- W2017556648 creator A5029801347 @default.
- W2017556648 creator A5046672535 @default.
- W2017556648 creator A5069400947 @default.
- W2017556648 creator A5084013212 @default.
- W2017556648 creator A5091740772 @default.
- W2017556648 date "1993-09-01" @default.
- W2017556648 modified "2023-10-17" @default.
- W2017556648 title "Microwave Spectrum and Molecular Structure of Methyl Cyanate" @default.
- W2017556648 doi "https://doi.org/10.1006/jmsp.1993.1220" @default.
- W2017556648 hasPublicationYear "1993" @default.
- W2017556648 type Work @default.
- W2017556648 sameAs 2017556648 @default.
- W2017556648 citedByCount "10" @default.
- W2017556648 countsByYear W20175566482016 @default.
- W2017556648 crossrefType "journal-article" @default.
- W2017556648 hasAuthorship W2017556648A5013893275 @default.
- W2017556648 hasAuthorship W2017556648A5014838749 @default.
- W2017556648 hasAuthorship W2017556648A5029801347 @default.
- W2017556648 hasAuthorship W2017556648A5046672535 @default.
- W2017556648 hasAuthorship W2017556648A5069400947 @default.
- W2017556648 hasAuthorship W2017556648A5084013212 @default.
- W2017556648 hasAuthorship W2017556648A5091740772 @default.
- W2017556648 hasConcept C121332964 @default.
- W2017556648 hasConcept C138211643 @default.
- W2017556648 hasConcept C155860418 @default.
- W2017556648 hasConcept C159985019 @default.
- W2017556648 hasConcept C178790620 @default.
- W2017556648 hasConcept C185592680 @default.
- W2017556648 hasConcept C188027245 @default.
- W2017556648 hasConcept C192562407 @default.
- W2017556648 hasConcept C193547582 @default.
- W2017556648 hasConcept C2779195922 @default.
- W2017556648 hasConcept C32909587 @default.
- W2017556648 hasConcept C44838205 @default.
- W2017556648 hasConcept C46141821 @default.
- W2017556648 hasConcept C62520636 @default.
- W2017556648 hasConcept C8010536 @default.
- W2017556648 hasConceptScore W2017556648C121332964 @default.
- W2017556648 hasConceptScore W2017556648C138211643 @default.
- W2017556648 hasConceptScore W2017556648C155860418 @default.
- W2017556648 hasConceptScore W2017556648C159985019 @default.
- W2017556648 hasConceptScore W2017556648C178790620 @default.
- W2017556648 hasConceptScore W2017556648C185592680 @default.
- W2017556648 hasConceptScore W2017556648C188027245 @default.
- W2017556648 hasConceptScore W2017556648C192562407 @default.
- W2017556648 hasConceptScore W2017556648C193547582 @default.
- W2017556648 hasConceptScore W2017556648C2779195922 @default.
- W2017556648 hasConceptScore W2017556648C32909587 @default.
- W2017556648 hasConceptScore W2017556648C44838205 @default.
- W2017556648 hasConceptScore W2017556648C46141821 @default.
- W2017556648 hasConceptScore W2017556648C62520636 @default.
- W2017556648 hasConceptScore W2017556648C8010536 @default.
- W2017556648 hasIssue "1" @default.
- W2017556648 hasLocation W20175566481 @default.
- W2017556648 hasOpenAccess W2017556648 @default.
- W2017556648 hasPrimaryLocation W20175566481 @default.
- W2017556648 hasRelatedWork W1968436507 @default.
- W2017556648 hasRelatedWork W1981036791 @default.
- W2017556648 hasRelatedWork W1981529723 @default.
- W2017556648 hasRelatedWork W1988730207 @default.
- W2017556648 hasRelatedWork W2009789088 @default.
- W2017556648 hasRelatedWork W2014017601 @default.
- W2017556648 hasRelatedWork W2015399661 @default.
- W2017556648 hasRelatedWork W2063042271 @default.
- W2017556648 hasRelatedWork W281629811 @default.
- W2017556648 hasRelatedWork W354385381 @default.
- W2017556648 hasVolume "161" @default.
- W2017556648 isParatext "false" @default.
- W2017556648 isRetracted "false" @default.
- W2017556648 magId "2017556648" @default.
- W2017556648 workType "article" @default.