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• W2017579087 abstract "We determined the phase diagram and the equation of state (EoS) of TiH2 at high pressures up to 8.7 GPa and high temperatures up to 600 °C by in situ synchrotron radiation X-ray diffraction measurements. Compression induced strain inhibited the phase transition from the low-temperature bct phase to the high-temperature fcc phase, making the phase diagram difficult to determine. However, heating around 600 °C relieved the strain, and the phase boundary between the bct and fcc phases was elucidated. The phase transition temperature at ambient pressure increased from around room temperature to 200 °C at 8.7 GPa. The high temperature Birch–Murnaghan EoS was determined for the fcc phase. With the pressure derivative of the bulk modulus K′0 = 4.0, the following parameters were obtained: ambient bulk modulus K0 = 97.7 ± 0.2 GPa, ambient unit cell of the fcc phase V0 = 88.57 ± 0.02 Å3, temperature derivative of the bulk modulus at constant pressure (∂K/∂T)P = −0.01 ± 0.02, and volumetric thermal expansivity α = a + bT with a = 2.62 ± 1.4 × 10−5 and b = 5.5 ± 4.5 × 10−8. K0 of fcc TiH2 was close to those for pure Ti and bct TiH2 reported in previous studies." @default.
• W2017579087 created "2016-06-24" @default.
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• W2017579087 date "2013-01-01" @default.
• W2017579087 modified "2023-09-24" @default.
• W2017579087 title "Phase diagram and equation of state of TiH2 at high pressures and high temperatures" @default.
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• W2017579087 doi "https://doi.org/10.1016/j.jallcom.2012.08.083" @default.
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