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• W2017579225 abstract "Metalation of one aryl group of Ph3PNR (R = methyl, isopropyl) affords an easy access to the corresponding lithium salt, which in turn reacts with chlorophosphines R2PCl (R = Ph, i-Pr) to yield a new class of bidentate ligand featuring one iminophosphorane and one phosphino group. Reaction of the phenyl derivative with [Pd(COD)Cl2] yielded the expected six-membered palladacycle complex, which was structurally characterized. Extension of this new synthetic methodology toward the elaboration of enantiomerically pure tetradentate ligands has also been achieved." @default.
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• W2017579225 date "2006-05-13" @default.
• W2017579225 modified "2023-09-25" @default.
• W2017579225 title "Nitrogen-Assisted Ortho Lithiation: One-Pot Synthesis of New Classes of Bidentate and Tetradentate Mixed P∼N Ligands" @default.
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• W2017579225 doi "https://doi.org/10.1021/om060208e" @default.
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