FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017582658> ?p ?o ?g. }

• W2017582658 endingPage "7178" @default.
• W2017582658 startingPage "7164" @default.
• W2017582658 abstract "A global deperturbation is presented for all electronic states of NiH with T0 values below 0.3 eV. These states form an isolated group and are treated as components of a molecular ‘‘supermultiplet’’ which is derived from a nickel-centered 3d9 electron configuration such as that found in the 2D term of Ni+. Observed term energies for all low-lying states, including some vibrationally excited levels, are used in a least squares fit to the supermultiplet model. A crucial feature of the supermultiplet model is its employment, wherever possible, of atomic angular (e.g., L±‖LΛ〉=[L(L+1)−Λ(Λ±1)]1/2‖LΛ±1〉) and radial (e.g., spin–orbit coupling constants) matrix elements to define and constrain the molecular effective Hamiltonian. A relatively small number of adjustable parameters are required to represent the v=0 and 1, J=0.5–11.5 term values in the supermultiplet picture and accurately describe a variety of observations, which include large Ω doublings, unusually large and J, Ω, e/f-dependent Zeeman g values, and a symmetry-forbidden (ΔΛ=2) rotational pertubation. The number of independently adjustable parameters required by the supermultiplet model is significantly smaller than a standard 2Δ, 2Π, 2Σ+ deperturbation model. In addition, the fitted deperturbed (i.e., nonrelativistic and nonrotating) molecular constants for the 2Δ, 2Π, 2Σ+ components of the NiH supermultiplet are in better agreement with theoretical descriptions than previous empirical constants taken directly, without deperturbation, from spectra. The fit model also yields an empirical value of the (3d9)σ∼3d10 configuration mixing coefficient, which is relevant to a global understanding of the d9 and d10 states in the homologous NiH, PdH, PtH series of molecules." @default.
• W2017582658 created "2016-06-24" @default.
• W2017582658 creator A5038369135 @default.
• W2017582658 creator A5045958281 @default.
• W2017582658 creator A5048331270 @default.
• W2017582658 creator A5078723351 @default.
• W2017582658 date "1991-11-15" @default.
• W2017582658 modified "2023-10-16" @default.
• W2017582658 title "The electronic structure of NiH: The {Ni⁺3<i>d</i>⁹ ²<i>D</i>} supermultiplet" @default.
• W2017582658 cites W1964638494 @default.
• W2017582658 cites W1966577674 @default.
• W2017582658 cites W1967412563 @default.
• W2017582658 cites W1968751065 @default.
• W2017582658 cites W1970233717 @default.
• W2017582658 cites W1983265212 @default.
• W2017582658 cites W1993462895 @default.
• W2017582658 cites W1996102952 @default.
• W2017582658 cites W1998931034 @default.
• W2017582658 cites W1999695539 @default.
• W2017582658 cites W2002018491 @default.
• W2017582658 cites W2019587979 @default.
• W2017582658 cites W2022748454 @default.
• W2017582658 cites W2025706145 @default.
• W2017582658 cites W2028388922 @default.
• W2017582658 cites W2033368351 @default.
• W2017582658 cites W2038152895 @default.
• W2017582658 cites W2042673738 @default.
• W2017582658 cites W2044771629 @default.
• W2017582658 cites W2045629483 @default.
• W2017582658 cites W2048858115 @default.
• W2017582658 cites W2058239445 @default.
• W2017582658 cites W2058363981 @default.
• W2017582658 cites W2060882010 @default.
• W2017582658 cites W2061867189 @default.
• W2017582658 cites W2063482341 @default.
• W2017582658 cites W2065796284 @default.
• W2017582658 cites W2067153640 @default.
• W2017582658 cites W2068321111 @default.
• W2017582658 cites W2068627322 @default.
• W2017582658 cites W2073028985 @default.
• W2017582658 cites W2074750956 @default.
• W2017582658 cites W2080623820 @default.
• W2017582658 cites W2086715553 @default.
• W2017582658 cites W2088632085 @default.
• W2017582658 cites W2090458465 @default.
• W2017582658 cites W2094586557 @default.
• W2017582658 cites W2127347278 @default.
• W2017582658 cites W2769729434 @default.
• W2017582658 doi "https://doi.org/10.1063/1.461393" @default.
• W2017582658 hasPublicationYear "1991" @default.
• W2017582658 type Work @default.
• W2017582658 sameAs 2017582658 @default.
• W2017582658 citedByCount "51" @default.
• W2017582658 countsByYear W20175826582012 @default.
• W2017582658 countsByYear W20175826582013 @default.
• W2017582658 countsByYear W20175826582015 @default.
• W2017582658 countsByYear W20175826582016 @default.
• W2017582658 countsByYear W20175826582017 @default.
• W2017582658 countsByYear W20175826582018 @default.
• W2017582658 countsByYear W20175826582019 @default.
• W2017582658 countsByYear W20175826582020 @default.
• W2017582658 countsByYear W20175826582021 @default.
• W2017582658 crossrefType "journal-article" @default.
• W2017582658 hasAuthorship W2017582658A5038369135 @default.
• W2017582658 hasAuthorship W2017582658A5045958281 @default.
• W2017582658 hasAuthorship W2017582658A5048331270 @default.
• W2017582658 hasAuthorship W2017582658A5078723351 @default.
• W2017582658 hasConcept C105319627 @default.
• W2017582658 hasConcept C116674579 @default.
• W2017582658 hasConcept C121332964 @default.
• W2017582658 hasConcept C126255220 @default.
• W2017582658 hasConcept C130787639 @default.
• W2017582658 hasConcept C181500209 @default.
• W2017582658 hasConcept C183276030 @default.
• W2017582658 hasConcept C184779094 @default.
• W2017582658 hasConcept C185592680 @default.
• W2017582658 hasConcept C33923547 @default.
• W2017582658 hasConcept C4839761 @default.
• W2017582658 hasConcept C62520636 @default.
• W2017582658 hasConcept C78710322 @default.
• W2017582658 hasConcept C86025842 @default.
• W2017582658 hasConceptScore W2017582658C105319627 @default.
• W2017582658 hasConceptScore W2017582658C116674579 @default.
• W2017582658 hasConceptScore W2017582658C121332964 @default.
• W2017582658 hasConceptScore W2017582658C126255220 @default.
• W2017582658 hasConceptScore W2017582658C130787639 @default.
• W2017582658 hasConceptScore W2017582658C181500209 @default.
• W2017582658 hasConceptScore W2017582658C183276030 @default.
• W2017582658 hasConceptScore W2017582658C184779094 @default.
• W2017582658 hasConceptScore W2017582658C185592680 @default.
• W2017582658 hasConceptScore W2017582658C33923547 @default.
• W2017582658 hasConceptScore W2017582658C4839761 @default.
• W2017582658 hasConceptScore W2017582658C62520636 @default.
• W2017582658 hasConceptScore W2017582658C78710322 @default.
• W2017582658 hasConceptScore W2017582658C86025842 @default.
• W2017582658 hasIssue "10" @default.
• W2017582658 hasLocation W20175826581 @default.
• W2017582658 hasOpenAccess W2017582658 @default.

• next