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• W2017592723 abstract "Thermodynamic data on activities, activity coefficients, and free energies of mixing in SiO 2 ‐Al 2 O 3 solutions were calculated from the phase diagram. Positive deviations from ideal mixing in the thermodynamic data suggest a tendency for liquid immiscibility in both SiO 2 ‐ and Al 2 O 3 ‐rich compositions. The calculated data were used to estimate regions of liquid‐liquid immiscibility. A calculated metastable liquid miscibility gap with a consolute temperature of ∼1540 ° C at a critical composition of ∼36 mol% Al 2 O 3 was considered to be thermodynamically most probable; the gap extended from ∼11 to °49 mol% Al 2 O 3 at 1100 ° C. SiO 2 ‐rich glass compositions showed evidence of glass‐in‐glass phase separation when examined by direct transmission electron microscopy." @default.
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• W2017592723 date "1977-09-01" @default.
• W2017592723 modified "2023-10-07" @default.
• W2017592723 title "Calculated Thermodynamic Data and Metastable Immiscibility in the System SiO₂‐Al₂O₃" @default.
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• W2017592723 doi "https://doi.org/10.1111/j.1151-2916.1977.tb15525.x" @default.
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