Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017595992> ?p ?o ?g. }
- W2017595992 endingPage "2438" @default.
- W2017595992 startingPage "2426" @default.
- W2017595992 abstract "Well-defined diblock copolymers {PS-b-P(ϵ-CL)} and triblock terpolymers {PS-b-PI-b-P(ϵ-CL), PI-b-PS-b-P(ϵ-CL)} of polystyrene, PS, poly(ϵ-caprolactone), P(ϵ-CL), and polyisoprene, PI, were synthesized using CpTiCl2(OP) (P = PS, PS-b-PI, or PI-b-PS) as macroinitiator. Graft copolymers having polybutadiene, PBd, backbone and poly(n-hexyl isocyanate), PHIC, or P(ϵ-CL) branches {PBd-g-PHIC and PBd-g-P(ϵ-CL)} as well as block−graft terpolymers {PS-b-(PI-g-PHIC), PS-b-[PI-g-P(ϵ-CL)]} were also synthesized by performing hydroboration/oxidation reactions on the polydiene backbone and by transforming the introduced hydroxyl groups to initiation sites by reaction with CpTiCl3. Finally, PS(PHIC)2 and PS[P(ϵ-CL)]2 3-miktoarm star copolymers were synthesized using a heterofunctional initiator bearing one initiation site for atom transfer radical polymerization and two for titanium-mediated coordination polymerization. All intermediates and final products were characterized by size exclusion chromatography, equipped with refractive index and light scattering detectors, membrane osmometry, and 1H NMR spectroscopy." @default.
- W2017595992 created "2016-06-24" @default.
- W2017595992 creator A5006730233 @default.
- W2017595992 creator A5009359821 @default.
- W2017595992 creator A5065629023 @default.
- W2017595992 creator A5069464088 @default.
- W2017595992 creator A5075431760 @default.
- W2017595992 creator A5086909531 @default.
- W2017595992 date "2008-03-07" @default.
- W2017595992 modified "2023-09-29" @default.
- W2017595992 title "Complex Macromolecular Architectures Based on <i>n</i>-Hexyl Isocyanate and ϵ-Caprolactone Using Titanium-Mediated Coordination Polymerization" @default.
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