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- W2017599571 abstract "The palladium-catalyzed reaction of the captodative olefin 3-(p-nitrobenzoyloxy)-3-buten-2-one (1a) with aryl and vinyl halides gave coupled products 4-aryl- and 4-vinyl-3-(p-nitrobenzoyloxy)-3-buten-2-ones, 4 and 6 respectively, with high Z stereoselection. (Ph3P)2PdCl2 also catalyzed cross-coupling alkylation, phenylation and vinylation with trialkylorganostannanes and bromo olefin (Z)-4-bromo-3-(p-nitrobenzoyloxy)-3-buten-2-one (2), providing the corresponding trisubstituted alkenes. For the preparation of n-butyl substituted derivative (Z)-3-(p-nitrobenzoyloxy)-3-octen-2-one (8b), the transmetallation with n-BuZnCl was a more efficient method. Retention of the Z configuration of 2 was in all cases maintained." @default.
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- W2017599571 date "1996-06-01" @default.
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- W2017599571 title "Highly stereoselective palladium-catalyzed coupling reactions of captodative olefins acetylvinyl arenecarboxylates" @default.
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- W2017599571 doi "https://doi.org/10.1016/0022-328x(96)06112-8" @default.
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