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- W2017600650 abstract "The hydrogenation of methyl crotonate with CO and H2O is efficiently catalyzed by RhH2(O2COH)[P(i-Pr)3]2 or [RhCl(C7H8)]2/P(i-Pr)3/n-BuLi (C7H8=norbornadiene). Both catalyst precursors are shown to form the same active species; transRh(OH)(CO)[P(i-Pr)3]2. The catalytic activity of the system ([RhCl(C7H8)]2/phosphine/n-BuLi) increases with increase of the basicity of the phosphine ligands (phosphine=P(i-Pr)3>P(n-Bu)3>PPh(i-Pr)2>PPh2(i-Pr)>PPh3). This reaction is also applicable to the hydrogenation of the C=C bond of electronwithdrawing olefins and the C=O bond of ketones and aldehydes. Interestingly, the catalysis for the C=C bond, to which less electron-withdrawing groups are attached, gives dominantly aldehydes due to hydroformylation. The mechanism is also discussed." @default.
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- W2017600650 date "1981-12-01" @default.
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- W2017600650 title "Application of the Water-gas Shift Reaction. I. Hydrogenation and Hydroformylation Reactions of Olefins with Carbon Monoxide and Water Catalyzed by Rhodium Phosphine Complexes" @default.
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- W2017600650 doi "https://doi.org/10.1246/bcsj.54.3799" @default.
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