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• W2017604369 abstract "The reaction of Os4(CO)12(μ-H)4 with Me3NO followed by 1,4-bis(ferrocenyl)butadiyne (1) has yielded the tetraosmium product Os4(CO)11(μ-η2-FcCC(H)C2Fc)(μ-H)3 (5), Fc=C5H5FeC5H4 in 9% yield by decarbonylation and insertion of the 1,4-bis(ferrocenyl)butadiyne into one of the metal–hydrogen bonds in the cluster. Compound 5 was characterized by IR, 1H-NMR spectroscopy and single crystal X-ray diffraction analysis. The molecule contains a closed tetrahedral cluster of four osmium atoms with three bridging hydride ligands. One of the C–C triple bonds of 1 was inserted into one of the Os–H bonds to form a (bis-ferrocenyl)yneenyl ligand that bridges one edge of the cluster in a θ-π coordination mode. Compound 5 exhibits two one-electron oxidations for the ferrocenyl groups at E°=+0.443 and +0.486 V versus Ag/AgCl, ΔE°=0.043 V. This small difference indicates that there is little or no electronic communication between the two ferrocenyl groups." @default.
• W2017604369 created "2016-06-24" @default.
• W2017604369 creator A5025937252 @default.
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• W2017604369 date "2001-01-01" @default.
• W2017604369 modified "2023-09-25" @default.
• W2017604369 title "Insertion of bis-ferrocenylbutadiyne into an osmium hydride bond. The synthesis, structure and electrochemical response of Os4(CO)11(μ-η-Z-FcCC(H)C2Fc)(μ-H)3" @default.
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• W2017604369 doi "https://doi.org/10.1016/s0022-328x(00)00664-1" @default.
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