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- W2017617745 abstract "The theory for the d.c. polarographic current-potential profile with an ECE mechanism accompanied by nernstian behavior is examined. It is shown that a solution expressible in terms of the Matsuda-Ayabe ψ(ξ) function or the Koutecky F(χ) function is obtained readily with the aid of the expanding plane electrode model and the Koutecky steady-state approximation. Predicted effects of the chemical reaction rate on the shape of the polarograms are discussed. Good agreement is found between limiting currents calculated on the basis of the steady-state approximation and more rigorous numerical calculations for kt>1." @default.
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- W2017617745 title "D.C. polarography: On the theory for the current-potential profile with an ECE mechanism" @default.
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- W2017617745 doi "https://doi.org/10.1016/s0022-0728(70)80310-2" @default.
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