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- W2017628799 abstract "Rhodium-mediated cyclization of the α-diazo ester 1 proceeds with high diastereoselectivity, to give the trisubstituted cyclopentane 5. A computational model (ZINDO and Molecular Mechanics) based on our current mechanistic understanding of the reaction is presented. This model correctly predicts the dominant diastereomer from the cyclization of 1 and the eight (Table 2) other α-diazo esters studied thus far." @default.
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- W2017628799 title "Predicting the Diastereoselectivity of Rh-Mediated Intramolecular C−H Insertion" @default.
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