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- W2017635613 abstract "Abstract The surface chemistry of 1,2-propanediol (PDO) has been studied on oxygen precovered Pd(111) using temperature programmed desorption (TPD) and high-resolution electron energy loss spectroscopy (HREELS). Adsorbed 1,2-propanedioxy (–OCH(CH 3 )CH 2 O–) forms from the activation of the O–H bonds. When the concentration of O (a) is large compared to 1,2-propanedioxy, no H 2 is produced and the dialkoxide reacts to form H 2 O, CO through decarbonylation, and CO 2 through decarboxylation. Unreacted oxygen also desorbs as O 2 at high temperature. Conversely, when the concentration of O (a) is small relative to 1,2-propanedioxy, the dialkoxide reacts to form decomposition products (H 2 , CO), oxidation products (H 2 O, glyoxal, methylglyoxal, formaldehyde) and deoxygenation products (ethylene, propylene). Co-adsorbed oxygen increases the overall coverage of PDO that can undergo decomposition, which in turn strongly influences decomposition activation barriers and products." @default.
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- W2017635613 date "2014-01-01" @default.
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- W2017635613 title "The influence of oxygen on the surface chemistry of 1,2-propanediol on Pd(111)" @default.
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- W2017635613 doi "https://doi.org/10.1016/j.susc.2013.09.016" @default.
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