FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017646667> ?p ?o ?g. }

• W2017646667 endingPage "752" @default.
• W2017646667 startingPage "727" @default.
• W2017646667 abstract "Abstract The Brewer-Engel valence-bond theory for bonding in metals and intermetallic phases has been employed to correlate the electrocatalytic features of both individual and composite transition metal catalysts for the hydrogen evolution reaction (h.e.r.). The basic concept of the Brewer-Engel valence-bond theory, which relates the electronic state of lowest energy level or the structure of atoms, with the corresponding phase structure in both individual metallic and multicomponent intermetallic systems, is also given. On the basis of the Brewer intermetallic bonding model as a generalized Lewis acid-base reaction, it is pointed out that whenever metals of the left half of the transition series, having empty or half-filled vacant d-orbitals, are alloyed with metals of the right half of the transition series having internally paired d-electrons not available for bonding in the pure metal, which proceeds with definite charge transfer, there arises a well-pronounced synergism in electrocatalysis for the h.e.r., which often exceeds the individual catalytic effects of precious metals by themselves or in combination (the synergism condition) and approaches reversible behaviour within a wide range of current density. It is inferred that the maximum electrocatalytic activity extends to the composite d-metal catalysts of improved d-orbital overlap in intermetallic phases of highest symmetry and minimal entropy, such as Laves phases and A15 or Cr3Si types such as MoCo3, WNi3, VNi3, HfPd3, ZrPt3, LaNi5, HfPt3, that the Brewer theory for intermetallic bonding predicts for the most stable systems. The theoretical explanation for an optimal (d8) electronic configuration in both individual and composite synergetic electrocatalytic systems is given and compared with similar catalytic processes. The induced hydridic feature of high activity synergetic transition metal composite electrocatalysts is also pointed out." @default.
• W2017646667 created "2016-06-24" @default.
• W2017646667 creator A5065076084 @default.
• W2017646667 date "1987-01-01" @default.
• W2017646667 modified "2023-10-18" @default.
• W2017646667 title "Advances in electrocatalysis for hydrogen evolution in the light of the Brewer-Engel valence-bond theory☆" @default.
• W2017646667 cites W1491453071 @default.
• W2017646667 cites W1497919872 @default.
• W2017646667 cites W1607286065 @default.
• W2017646667 cites W1816450589 @default.
• W2017646667 cites W1967674568 @default.
• W2017646667 cites W1979288745 @default.
• W2017646667 cites W1985553102 @default.
• W2017646667 cites W1992193938 @default.
• W2017646667 cites W1992637318 @default.
• W2017646667 cites W1993470615 @default.
• W2017646667 cites W1995214773 @default.
• W2017646667 cites W1998500075 @default.
• W2017646667 cites W1998567812 @default.
• W2017646667 cites W2017960977 @default.
• W2017646667 cites W2020874777 @default.
• W2017646667 cites W2021318889 @default.
• W2017646667 cites W2036844141 @default.
• W2017646667 cites W2038194685 @default.
• W2017646667 cites W2038990381 @default.
• W2017646667 cites W2040871324 @default.
• W2017646667 cites W2041210507 @default.
• W2017646667 cites W2043995121 @default.
• W2017646667 cites W2044309626 @default.
• W2017646667 cites W2046790280 @default.
• W2017646667 cites W2048738601 @default.
• W2017646667 cites W2050507128 @default.
• W2017646667 cites W2051623020 @default.
• W2017646667 cites W2052692235 @default.
• W2017646667 cites W2052953466 @default.
• W2017646667 cites W2054465146 @default.
• W2017646667 cites W2058657273 @default.
• W2017646667 cites W2059390162 @default.
• W2017646667 cites W2061362667 @default.
• W2017646667 cites W2062027658 @default.
• W2017646667 cites W2066568104 @default.
• W2017646667 cites W2070688246 @default.
• W2017646667 cites W2080754362 @default.
• W2017646667 cites W2085208616 @default.
• W2017646667 cites W2089104547 @default.
• W2017646667 cites W2090221158 @default.
• W2017646667 cites W2171613439 @default.
• W2017646667 cites W2314211154 @default.
• W2017646667 cites W2780678568 @default.
• W2017646667 cites W2908916379 @default.
• W2017646667 cites W610820825 @default.
• W2017646667 cites W2051313597 @default.
• W2017646667 doi "https://doi.org/10.1016/0360-3199(87)90090-5" @default.
• W2017646667 hasPublicationYear "1987" @default.
• W2017646667 type Work @default.
• W2017646667 sameAs 2017646667 @default.
• W2017646667 citedByCount "168" @default.
• W2017646667 countsByYear W20176466672012 @default.
• W2017646667 countsByYear W20176466672013 @default.
• W2017646667 countsByYear W20176466672014 @default.
• W2017646667 countsByYear W20176466672015 @default.
• W2017646667 countsByYear W20176466672016 @default.
• W2017646667 countsByYear W20176466672017 @default.
• W2017646667 countsByYear W20176466672018 @default.
• W2017646667 countsByYear W20176466672019 @default.
• W2017646667 countsByYear W20176466672020 @default.
• W2017646667 countsByYear W20176466672021 @default.
• W2017646667 countsByYear W20176466672022 @default.
• W2017646667 countsByYear W20176466672023 @default.
• W2017646667 crossrefType "journal-article" @default.
• W2017646667 hasAuthorship W2017646667A5065076084 @default.
• W2017646667 hasConcept C10138342 @default.
• W2017646667 hasConcept C121332964 @default.
• W2017646667 hasConcept C147120987 @default.
• W2017646667 hasConcept C147789679 @default.
• W2017646667 hasConcept C162324750 @default.
• W2017646667 hasConcept C168900304 @default.
• W2017646667 hasConcept C17525397 @default.
• W2017646667 hasConcept C178429038 @default.
• W2017646667 hasConcept C178790620 @default.
• W2017646667 hasConcept C185592680 @default.
• W2017646667 hasConcept C189394030 @default.
• W2017646667 hasConcept C192562407 @default.
• W2017646667 hasConcept C33989665 @default.
• W2017646667 hasConcept C52859227 @default.
• W2017646667 hasConcept C62520636 @default.
• W2017646667 hasConcept C69738904 @default.
• W2017646667 hasConceptScore W2017646667C10138342 @default.
• W2017646667 hasConceptScore W2017646667C121332964 @default.
• W2017646667 hasConceptScore W2017646667C147120987 @default.
• W2017646667 hasConceptScore W2017646667C147789679 @default.
• W2017646667 hasConceptScore W2017646667C162324750 @default.
• W2017646667 hasConceptScore W2017646667C168900304 @default.
• W2017646667 hasConceptScore W2017646667C17525397 @default.
• W2017646667 hasConceptScore W2017646667C178429038 @default.
• W2017646667 hasConceptScore W2017646667C178790620 @default.
• W2017646667 hasConceptScore W2017646667C185592680 @default.
• W2017646667 hasConceptScore W2017646667C189394030 @default.

• next