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- W2017651465 abstract "High quality poly(5-methylindole) (P5MeI) films, especially with good fluorescence properties, were synthesized electrochemically by direct anodic oxidation of 5-methylindole in boron trifluoride diethyl etherate (BFEE) containing additional 50% diethyl ether (EE) (by volume). The oxidation potential onset of 5-methylindole in this medium was measured to be only 0.84 V vs. SCE, which was much lower than that determined in acetonitrile + 0.1 mol L−1 TBATFB (1.08 V vs. SCE). P5MeI films obtained from this medium showed good electrochemical behavior and good thermal stability with conductivity of 10−2 S cm−1, indicating that BFEE was a better medium than acetonitrile for the electrosyntheses of P5MeI films. Dedoped P5MeI films were thoroughly soluble in strong polar solvent such as dimethyl sulfoxide (DMSO). 1H NMR spectroscopy and FT infrared spectrum of dedoped P5MeI films strongly suggested that the monomers were linked via the positions 2 and 3. Fluorescent spectral studies indicated that P5MeI was a good violet–blue light emitter with the excitation and emission wavelength of 310 nm and 418 nm, respectively. To the best of our knowledge, this is the first case that 5-methyl group substituted polyindole films with good fluorescence properties can be electrodeposited." @default.
- W2017651465 created "2016-06-24" @default.
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- W2017651465 date "2006-06-01" @default.
- W2017651465 modified "2023-10-16" @default.
- W2017651465 title "Electrosyntheses of high quality poly(5-methylindole) films in mixed electrolytes of boron trifluoride diethyl etherate and diethyl ether" @default.
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- W2017651465 doi "https://doi.org/10.1016/j.eurpolymj.2005.12.009" @default.
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