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- W2017651504 abstract "Hydrogen-atom reaction rates with thin solid propylene films were studied at 77°K. Propylene was deposited on the walls of a quartz resonance cavity of an ESR spectrometer and hydrogen-atom concentrations were monitored during reaction. The hydrogen atoms were produced in a 2450 Mc/sec microwave discharge external to the cavity and either diffused into or were pumped through the reaction zone. The products of the reaction were found to be propane and 2,3-dimethylbutane. The ratio of propane to 2,3-dimethylbutane in the products increased as the average hydrogen-atom concentration in the reactor increased. The product distribution and the variation of this distribution with hydrogen-atom concentration may be explained by the following sequence of reactions: CH3–CH=CH2+H→ lim k1CH3–ĊH–CH3,2 CH3–ĊH–CH3→ lim k2CH3–CH2–CH3+CH3–CH=CH2,[Complex chemical formula]CH3–ĊH–CH3+H→ lim k4CH3–CH2–CH3. The rate constant k1 was found to be 1.8×106 cc/mole·sec at 77°K assuming that the monitored hydrogen-atom concentration was equal to that in the reaction zone." @default.
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- W2017651504 title "Reaction of Atomic Hydrogen with Propylene at 77°K as Studied by Electron Spin Resonance" @default.
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- W2017651504 doi "https://doi.org/10.1063/1.1695914" @default.
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