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• W2017659018 abstract "Free heterogeneous argon-krypton clusters have been produced by coexpansion and investigated by means of x-ray photoelectron spectroscopy. By examining cluster surface and bulk binding energy shifts, relative intensities, and peak widths, we show that in the mixed argon-krypton clusters the krypton atoms favor the bulk and argon atoms are pushed to the surface. Furthermore, we show that krypton atoms in the surface layer occupy high-coordination sites and that heterogeneous argon-krypton clusters produced by coexpansion show the same surface structure as argon host clusters doped with krypton. These observations are supported by site-dependent calculations of chemical shifts." @default.
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• W2017659018 date "2006-10-30" @default.
• W2017659018 modified "2023-10-14" @default.
• W2017659018 title "Preferential site occupancy observed in coexpanded argon-krypton clusters" @default.
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• W2017659018 doi "https://doi.org/10.1103/physreva.74.043206" @default.
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