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• W2017666021 abstract "Abstract Smooth, epitaxial cerium dioxide thin films have been grown in-situ in the 450–650°C temperature range on (001) yttria-stabilized zirconia (YSZ) substrates by metal–organic chemical vapor deposition (MOCVD) using a new fluorine-free liquid Ce precursor. As assessed by X-ray diffraction, transmission electron microscopy (TEM), and high-resolution electron microscopy (HREM), the epitaxial films exhibit a columnar microstructure with atomically abrupt film-substrate interfaces and with only minor bending of the crystal plane parallel to the substrate surface near the interface and at the column boundaries. With fixed precursor temperature and gas flow rate, the CeO 2 growth rate decreases from ∼10 A/min at 450°C to ∼6.5 A/min at 540°C. The root-mean-square roughness of the films also decreases from 15.5 A at 450°C to 4.3 A at 540°C. High-quality, epitaxial YBa 2 C 3 O 7− x films have been successfully deposited on these MOCVD-derived CeO 2 films grown at temperatures as low as 540°C. They exhibit T c =86.5 K and J c =1.08×10 6 A/cm 2 at 77.4 K." @default.
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• W2017666021 date "1999-07-01" @default.
• W2017666021 modified "2023-10-16" @default.
• W2017666021 title "Buffers for high temperature superconductor coatings. Low temperature growth of CeO2 films by metal–organic chemical vapor deposition and their implementation as buffers" @default.
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• W2017666021 doi "https://doi.org/10.1016/s0921-4534(99)00354-8" @default.
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