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• W2017674504 abstract "A laboratory-scale atomic layer deposition (ALD) reactor system model is derived for alumina deposition using trimethylaluminum and water as precursors. Model components describing the precursor thermophysical properties, reactor-scale gas-phase dynamics and surface reaction kinetics derived from absolute reaction rate theory are integrated to simulate the complete reactor system. Limit-cycle solutions defining continuous cyclic ALD reactor operation are computed with a fixed point algorithm based on collocation discretization in time, resulting in an unambiguous definition of film growth-per-cycle (gpc). A key finding of this study is that unintended chemical vapor deposition conditions can mask regions of operation that would otherwise correspond to ideal saturating ALD operation. The use of the simulator for assisting in process design decisions is presented." @default.
• W2017674504 created "2016-06-24" @default.
• W2017674504 creator A5038724247 @default.
• W2017674504 creator A5073681453 @default.
• W2017674504 date "2013-08-19" @default.
• W2017674504 modified "2023-09-23" @default.
• W2017674504 title "Dynamic Modeling for the Design and Cyclic Operation of an Atomic Layer Deposition (ALD) Reactor" @default.
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• W2017674504 doi "https://doi.org/10.3390/pr1020128" @default.
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