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• W2017677773 abstract "[MeC5H4(CO)2(NO)Mn]PF6 (1) reagiert mit zwei Äquivalenten Me3PCH2 unter Ylidaddition am Carbonyl-Kohlenstoff und Umylidierung zu MeC5H4(CO)(NO)MnC(O)HCPMe3 (3) und [Me4P]PF6 (2). 3 wird außerdem aus dem Mangan-Kation und Me3PCHSiMe3 bzw. aus MeC5H4(CO)(NO)MnC(O)OMe (6) und Me3PCH2 erhalten. Einwirkung von MeX (X = I, SO3F) auf 3 ergibt ausschließlich die Manganacyl-Phosphoniumsalze [MeC5H4(CO)(NO)Mn-C(O)CHMePMe3] X (7a, b). Die neuen Mangan-Komplexe werden NMR- und IR-spektroskopisch charakterisiert. Reactions of Metal Coordinated Carbon Monoxide with Ylides, V. Synthesis and Methylation of a Neutral Manganeseacyl-Phosphorus Ylide [MeC5H4(CO)2(NO)Mn]PF6 (1) reacts with two equivalents Me3PCH2 via ylide addition at the carbonyl carbon and transylidation to give MeC5H4(CO)(NO)MnC(O)HCPMe3 (3) and [Me4P]PF6 (2). In addition, 3 is obtained from the manganese cation and Me3PCHSiMe3 or from MeC5H4(CO)(NO)MnC(O)OMe (6) and Me3PCH2, respectively. Treatment of 3 with MeX (X = I, SO3F) exclusively yields the manganeseacyl phosphonium salts [MeC5H4(CO)-(NO)MnC(O)CHMePMe3]X (7a,b). The new manganese complexes are characterized by NMR and IR spectroscopy." @default.
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• W2017677773 date "1982-04-01" @default.
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• W2017677773 title "Zur Reaktion von Metall-koordiniertem Kohlenmonoxid mit Yliden, V. Darstellung und Methylierung eines neutralen Manganacyl-Phosphorylids" @default.
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• W2017677773 doi "https://doi.org/10.1002/cber.19821150426" @default.
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