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• W2017681246 startingPage "1595" @default.
• W2017681246 abstract "Abstract A bis(imidazolidine)pyridine (PyBidine)–Cu(OTf) 2 complex catalyzing the endo‐selective [3+2] cycloaddition of nitroalkenes with imino esters was applied to the reaction of methyleneindolinones with imino esters to afford spiro[pyrrolidin‐3,3′‐oxindole]s in up to 98 % ee. X‐ray crystallographic analysis of the PyBidine–Cu(OTf) 2 complex and DFT calculations suggested that an intermediate Cu enolate of the imino ester reacts with nitroalkenes or methyleneindolinones, which are activated by NH‐hydrogen bonding with the PyBidine–Cu(OTf) 2 catalyst." @default.
• W2017681246 created "2016-06-24" @default.
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• W2017681246 date "2014-12-09" @default.
• W2017681246 modified "2023-10-18" @default.
• W2017681246 title "PyBidine-Cu(OTf)₂-Catalyzed Asymmetric [3+2] Cycloaddition with Imino Esters: Harmony of Cu-Lewis Acid and Imidazolidine-NH Hydrogen Bonding in Concerto Catalysis" @default.
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• W2017681246 doi "https://doi.org/10.1002/anie.201410782" @default.
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