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- W2017683886 abstract "The radical adducts resulting from the reaction between group IVB organometallic radicals MR3 (M = Si, Ge, Sn; R = alkyl or aryl) and a number of thioketones of the chromone and flavone series have been investigated by ESR spectroscopy. The spectral parameters obtained for these species have been compared with those of similar adducts of the corresponding ketones. Both classes of radicals adopt an orthogonal conformation, and the differences between the former and the latter paramagnetic species can be accounted for by the different electronegativity of oxygen and sulphur. the effects of substitution of the heterocyclic oxygen with a sulphur or selenium atom on the spin density distribution are likewise explained. INDO calculations have been carried out on the model systems CH2XSiH3 (X = O, S)." @default.
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- W2017683886 date "1981-11-01" @default.
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- W2017683886 title "Spin adducts of group IVB organometallic radicals with Thioketones. an esr study" @default.
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- W2017683886 doi "https://doi.org/10.1016/s0022-328x(00)81027-x" @default.
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