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- W2017687631 abstract "The electrophilic C−H palladation and Heck-type alkenylation of the tetrahydro[1,2-a]pyrimidine scaffold leads to exclusive formation of the C(7) adducts, and this palladium-catalyzed process is applicable to a broad range of alkenyl components. Mechanistic studies suggest that palladation is selective for C(7), and there was no evidence for C(9) metalation; the latter corresponds to the pathway observed previously with N-methylpyridone." @default.
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- W2017687631 date "2009-05-27" @default.
- W2017687631 modified "2023-10-16" @default.
- W2017687631 title "Direct and Regioselective C−H Alkenylation of Tetrahydropyrido[1,2-<i>a</i>]pyrimidines" @default.
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- W2017687631 doi "https://doi.org/10.1021/ol900627q" @default.
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