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- W2017690052 abstract "The theory of the $l$-type doubling for axially symmetric polyatomic molecules is applied to molecules belonging to the symmetry groups ${C}_{4v}$ and ${V}_{d}$. It is shown that here $l$-type doubling may be expected in both degenerate Coriolis levels (referring to a positive and a negative product of the quantum numbers $K$ and $l$, respectively). A detailed analysis of a pyramidal $X{Y}_{4}$ model reveals that the doubling in these two levels is of the same order. On the basis of our discussion a microwave absorption pattern is predicted for the transitions $J=1ensuremath{rightarrow}J=2$, $ensuremath{Delta}K=0$, where a molecule of ${C}_{4v}$ or ${V}_{d}$ symmetry is in an excited degenerate vibration state. An interesting example may be provided by I${mathrm{F}}_{5}$ if this molecule has the ${C}_{4v}$ structure recently proposed." @default.
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- W2017690052 title "A Note Concerning<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>l</mml:mi></mml:math>-Type Doubling in Axially Symmetric Molecules, in Particular with Reference to Molecules Belonging to the Symmetry Groups<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi>C</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn><mml:mi>v</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math>and<mml:math xmlns:mml=http://www.…" @default.
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- W2017690052 doi "https://doi.org/10.1103/physrev.83.741" @default.
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