Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017691268> ?p ?o ?g. }
- W2017691268 endingPage "360" @default.
- W2017691268 startingPage "351" @default.
- W2017691268 abstract "Alpha- and beta-protonated naphthalenes (α- and β-HN+) were investigated by electronic absorption and fluorescence spectroscopies in 6 K neon matrixes using a mass-selected C10H9+ ion beam. The absorption spectra reveal S1/S2 ← S0 transitions with onsets at 502.1 and 396.1 nm for α-HN+, and 534.5 and 322.3 nm in the case of β-HN+. Wavelength-dispersed fluorescence was detected for α-HN+, starting at 504.4 nm. Light-induced α-HN+ → β-HN+ isomerization was observed upon S2 ← S0 excitation of α-HN+, whereas β-HN+ relaxed back into the more stable alpha form either upon excitation to S1 or via thermal population of the ground state vibrational levels near the top of the energy barrier between the two isomers. The intramolecular proton transfer leading to the α-HN+ ↔ β-HN+ photoisomerization is fully reversible. The observations are explained with the support of theoretical calculations on the ground- and excited states of the isomers, vertical excitation and adiabatic energies, minimum-energy pathways along the relevant reaction coordinates, and conical intersections between the electronic states." @default.
- W2017691268 created "2016-06-24" @default.
- W2017691268 creator A5019015370 @default.
- W2017691268 creator A5023447585 @default.
- W2017691268 creator A5025391036 @default.
- W2017691268 creator A5025791798 @default.
- W2017691268 creator A5045788277 @default.
- W2017691268 creator A5052567282 @default.
- W2017691268 date "2013-01-04" @default.
- W2017691268 modified "2023-09-27" @default.
- W2017691268 title "Electronic Spectra and Reversible Photoisomerization of Protonated Naphthalenes in Solid Neon" @default.
- W2017691268 cites W1484790455 @default.
- W2017691268 cites W1523678163 @default.
- W2017691268 cites W1657320774 @default.
- W2017691268 cites W1967361599 @default.
- W2017691268 cites W1972912854 @default.
- W2017691268 cites W1974479517 @default.
- W2017691268 cites W1975155744 @default.
- W2017691268 cites W1984450503 @default.
- W2017691268 cites W2001208471 @default.
- W2017691268 cites W2001465759 @default.
- W2017691268 cites W2002510197 @default.
- W2017691268 cites W2006696213 @default.
- W2017691268 cites W2007948505 @default.
- W2017691268 cites W2024751749 @default.
- W2017691268 cites W2028022118 @default.
- W2017691268 cites W2035187097 @default.
- W2017691268 cites W2035942888 @default.
- W2017691268 cites W2039427907 @default.
- W2017691268 cites W2041666405 @default.
- W2017691268 cites W2044039308 @default.
- W2017691268 cites W2044940178 @default.
- W2017691268 cites W2047583623 @default.
- W2017691268 cites W2047911108 @default.
- W2017691268 cites W2049356930 @default.
- W2017691268 cites W2054936178 @default.
- W2017691268 cites W2058273483 @default.
- W2017691268 cites W2069006374 @default.
- W2017691268 cites W2074944594 @default.
- W2017691268 cites W2076374820 @default.
- W2017691268 cites W2078061703 @default.
- W2017691268 cites W2082167360 @default.
- W2017691268 cites W2082691688 @default.
- W2017691268 cites W2088607897 @default.
- W2017691268 cites W2090791725 @default.
- W2017691268 cites W2091132159 @default.
- W2017691268 cites W2093244105 @default.
- W2017691268 cites W2103640477 @default.
- W2017691268 cites W2117978491 @default.
- W2017691268 cites W2121675549 @default.
- W2017691268 cites W2137018521 @default.
- W2017691268 cites W2138566603 @default.
- W2017691268 cites W2143315411 @default.
- W2017691268 cites W2143981217 @default.
- W2017691268 cites W2154405365 @default.
- W2017691268 cites W2163513345 @default.
- W2017691268 cites W2325468020 @default.
- W2017691268 cites W2334779785 @default.
- W2017691268 cites W2526587108 @default.
- W2017691268 cites W3005426092 @default.
- W2017691268 doi "https://doi.org/10.1021/jp310612j" @default.
- W2017691268 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/23244534" @default.
- W2017691268 hasPublicationYear "2013" @default.
- W2017691268 type Work @default.
- W2017691268 sameAs 2017691268 @default.
- W2017691268 citedByCount "15" @default.
- W2017691268 countsByYear W20176912682013 @default.
- W2017691268 countsByYear W20176912682014 @default.
- W2017691268 countsByYear W20176912682015 @default.
- W2017691268 countsByYear W20176912682016 @default.
- W2017691268 countsByYear W20176912682018 @default.
- W2017691268 countsByYear W20176912682020 @default.
- W2017691268 countsByYear W20176912682021 @default.
- W2017691268 countsByYear W20176912682022 @default.
- W2017691268 crossrefType "journal-article" @default.
- W2017691268 hasAuthorship W2017691268A5019015370 @default.
- W2017691268 hasAuthorship W2017691268A5023447585 @default.
- W2017691268 hasAuthorship W2017691268A5025391036 @default.
- W2017691268 hasAuthorship W2017691268A5025791798 @default.
- W2017691268 hasAuthorship W2017691268A5045788277 @default.
- W2017691268 hasAuthorship W2017691268A5052567282 @default.
- W2017691268 hasConcept C119824511 @default.
- W2017691268 hasConcept C121332964 @default.
- W2017691268 hasConcept C126661725 @default.
- W2017691268 hasConcept C1276947 @default.
- W2017691268 hasConcept C145148216 @default.
- W2017691268 hasConcept C161790260 @default.
- W2017691268 hasConcept C178790620 @default.
- W2017691268 hasConcept C181500209 @default.
- W2017691268 hasConcept C184779094 @default.
- W2017691268 hasConcept C185592680 @default.
- W2017691268 hasConcept C30095370 @default.
- W2017691268 hasConcept C4839761 @default.
- W2017691268 hasConcept C522602180 @default.
- W2017691268 hasConcept C547737533 @default.
- W2017691268 hasConcept C55493867 @default.
- W2017691268 hasConcept C62520636 @default.
- W2017691268 hasConcept C69523127 @default.