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- W2017692506 abstract "The rate constants (log k) for solvolysis of 2-, 3-, and 4-substituted bicyclo[2.2.2]octyl p-nitrobenzenesulfonates 10, 11 and 12, respectively, correlate linearly with the corresponding inductive substituent constants s̀. The formation of the ion pairs 9 is, therefore, controlled by the I effect of neighboring substituents. It follows from the corresponding reaction constants ρ1 of −1.54, −1.12, and −1.22 that inductivity is highest at the positions α to C(1). It is lower and practically equal at the β- and γ-positions. Therefore, charge dispersal is similar to that previously observed in the quinuclidinium ion 7." @default.
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- W2017692506 title "Polar Effects. Part 14. Inductive Charge Dispersal in Bicyclo[2.2.2]oct-1-yl Cations" @default.
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- W2017692506 doi "https://doi.org/10.1002/hlca.19850680810" @default.
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