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- W2017693902 endingPage "679" @default.
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- W2017693902 abstract "A linear free energy relationship, LFER, has been used to correlate 150 values of gas–chloroform partition coefficients, as log Lchl with a standard deviation, sd, of 0.23 log units, a correlation coefficient r2 of 0.985, and an F‐statistic of 1919. The equation reveals that bulk chloroform is dipolar/polarizable, of little hydrogen‐bond basicity, but as strong a hydrogen‐bond acid as bulk methanol or bulk ethanol. However, the main influence on gaseous solubility in chloroform is due to solute–solvent London dispersion interactions. A slightly modified LFER has been used to correlate 302 values of water–chloroform partition coefficients, as log Pchl. The correlation equation predicts log Pchl for a further 34 compounds not used in the equation with sd = 0.17 log units. When the LFER is applied to all 335 log Pchl values, the resulting equation has sd = 0.25, r2 = 0.971, and F = 2218." @default.
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- W2017693902 date "1999-07-01" @default.
- W2017693902 modified "2023-09-27" @default.
- W2017693902 title "Correlation and estimation of gas–chloroform and water–chloroform partition coefficients by a linear free energy relationship method" @default.
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- W2017693902 doi "https://doi.org/10.1021/js990008a" @default.
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