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- W2017697318 abstract "Abstract The tert-butyl cation is formed in the reaction of tert-BuCl with AlCl 3 or GaCl 3 in anhydrous liquid HCl as a solvent, or of tert-BuBr with AlBr 3 in HBr. At - 30 °C solutions of [C(CH 3 ) 3 + ] are stable. At room temperature very slow decomposition occurs over months. In the systems BCI 3 /HCl, InCl 3 /HCl and BBr 3 /HBr no formation of [C(CH 3 ) 3+ ] from the corresponding tert-butyl halide was observed. The tert-amyl cation can be stabilized only in AlBr 3 /HBr. The iso-propyl cation is not stable in any of the systems investigated. The ability of the Lewis acids employed to form carbenium ions corresponds with their catalytic activity in Friedel-Crafts alkylations." @default.
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- W2017697318 date "1979-04-01" @default.
- W2017697318 modified "2023-10-14" @default.
- W2017697318 title "Bildung von Alkylcarbenium-Ionen im System Aluminium-(Gallium-)halogenid/Halogenwasserstoff / Formation of Alkylcarbenium Ions in the System Aluminium (Gallium) Halide/ Hydrogen Halide" @default.
- W2017697318 doi "https://doi.org/10.1515/znb-1979-0405" @default.
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