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- W2017702765 abstract "The composition of anodic films on iron formed at different potentials in neutral solutions has been investigated by in-situ UV–vis and IR spectroscopies in the presence of PO43−, a non-contaminant inhibitor used in anticorrosive paints. Optical and electrochemical determinations were used to detect and characterize two well-defined current waves in the active region of Fe and a following passive zone at more positive potentials. The response has been associated with the presence on the surface, in the dissolution zone, of Fe3II[PO4]2 as the main species and probably some [FeIIIPO4]. [FeIIIPO4] has been detected in the passive region by in-situ IR spectroscopy. Only minor amounts of Fe2+ and Fe3+ species in solution have been detected optically. These phosphated overlayers are believed to provide extra protective properties to the passivating film." @default.
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- W2017702765 date "2000-02-01" @default.
- W2017702765 modified "2023-09-27" @default.
- W2017702765 title "In-situ spectroelectrochemistry (UV–visible and infrared) of anodic films on iron in neutral phosphate solutions" @default.
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- W2017702765 doi "https://doi.org/10.1016/s0013-4686(99)00393-x" @default.
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