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• W2017703115 abstract "We have achieved measuring four optical parameters simultaneously, namely, linear birefringence (LB), circular birefringence (CB), linear dichroism (LD), and circular dichroism (CD), of single crystals of Λ-(+)589- and Δ-(−)589-tris(ethylenediamine) cobalt(III) triiodide monohydrate (1) along the <001> plane at the fixed wavelength (514.5 nm). Such measurements are possible only when the High Accuracy Universal Polarimeter (HAUP) is employed; it is called the extended HAUP method. Our experimental results showed that both LB and LD of the Λ-(+)589-(1) crystal have the same magnitude as those of the Δ-(−)589-(1) crystal. It was also revealed for the first time that the CB data of crystals of Λ-(+)589-(1) and Δ-(−)589-(1) are almost of the same magnitude, but are of opposite sign, reflecting their opposite absolute configurations. On the other hand, although the CD data obtained for Λ-(+)589-(1) is almost three times larger than that for Δ-(−)589-(1,) these CD data are also opposite in sign, as expected from the opposite chirality of crystals. Chirality 16:286–293, 2004. © 2004 Wiley-Liss, Inc." @default.
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• W2017703115 date "2004-01-01" @default.
• W2017703115 modified "2023-10-16" @default.
• W2017703115 title "Measurement of circular birefringence and circular dichroism of the single crystals of ?-(+)589- and ?-(?)589-tris(ethylenediamine)cobalt(III) triiodide monohydrate by the extended HAUP method" @default.
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• W2017703115 doi "https://doi.org/10.1002/chir.20029" @default.
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