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- W2017703578 abstract "Abstract The 13 C NMR spectra of thiacyclopentane (thiolane) and its mono‐ and dimethyl derivatives at positions other than the heteroatom are reported. The 13 C shieldings are found to be consistent with a description of these compounds in terms of equilibria between half‐chair conformers. An attempt has been made to establish the axial or equatorial preference of methyl groups adjacent to, or removed from, the sulphur atom in these systems. In agreement with previous observations on thiacyclohexanes (thianes), the conformational preference of a methyl group for the equatorial orientation is greater at the β than at the α position." @default.
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- W2017703578 date "1980-04-01" @default.
- W2017703578 modified "2023-10-18" @default.
- W2017703578 title "13C chemical shifts and conformational analysis of methyl substituted thiacyclopentanes" @default.
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- W2017703578 doi "https://doi.org/10.1002/mrc.1270130414" @default.
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