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- W2017706446 abstract "By treatment with a catalytic amount of DBU in DCM, N-p-toluenesulphonyl carbamates 6a–c, prepared starting from the corresponding Baylis–Hillman adducts, gave (E)-2-(p-toluenesulphonylaminomethyl)propenoates 3a–c, exclusively. On the contrary, changing DABCO for DBU, 2-methylene-3-p-toluenesulfonylamino esters 4a–f were obtained in good yield starting from N-p-toluenesulphonyl carbamates 6a–f. In analogy, N-acyl carbamates 9a–f were treated with DABCO in DCM to give the 2-methylene-3-acylamino esters 5a–f." @default.
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- W2017706446 date "2002-03-01" @default.
- W2017706446 modified "2023-10-16" @default.
- W2017706446 title "Synthesis of unsaturated β-amino acid derivatives from carbamates of the Baylis–Hillman products" @default.
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- W2017706446 doi "https://doi.org/10.1016/s0040-4039(02)00233-2" @default.
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